Biochemistry (Board Review Series) - download pdf or read online

By Dawn B. Marks

ISBN-10: 0683055976

ISBN-13: 9780683055979

Used this e-book for the 1st yr miniboard in med tuition. It used to be a superb evaluation. not anything extraordinary.

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Both intracellular and extracellular roles for inositol polyphosphates have been proposed. Inositol hexaphosphate (phytate) was discovered as a component of cereals over 100 years ago, and before the disease rickets became treatable with vitamin D, it was imperative to remove this substance from foods because of the rachitogenic effect of its presence in the diet, as a result of the chelation of dietary calcium in the gut. Inositol polyphosphates other than phytate, particularly those having vicinal phosphates are also effective C a chelating agents.

Selective allylation of the equatorial hydrogen group at C-1 proceeded easily with allyl bromide and NaOH in benzene. After benzylation of the remaining hydroxyl, deallylation was achieved by isomerization with tris(triphenylphosphine) rhodium chloride. Subsequent acidic hydrolysis afforded the key synthetic intermediate, D-2,3,6-tri-0-benzyl-myo-inositol (10). The triol 10 was perphosphorylated with dianilinophosphoric chloride (DAPC). ; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

Nature 1989, 334, 661-665. 16. Hannun, Υ. ; Loomis, C. ; Merrill, A. H . ; Bell, R. M . J. Biol. Chem. 1986, 261, 12604-12609. 17. Danoff, S. ; Snyder, S. H. Biochem. J. 1988, 254, 701-705. 18. Nahorski, S. ; Potter, Β. V. L. Trends Pharmacol. Sci. 1989, 10, 139-144. 19. Moyer, J. ; Baker, D. C. Mol. Pharmacol. 1988, 33, 683-689. 20. ; Siren, M . ; Bergelin, I. Agents Actions 1990, 29, 68-70. 21. Vallejo, M . ; Hanley, M . R. Nature 1987, 330, 656-658. 22. Nicoletti, F . ; Bruno, V . ; Copani, Α .

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Biochemistry (Board Review Series) by Dawn B. Marks

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